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Palladium‐Catalyzed Intramolecular [3C+2C] Cycloaddition of Alkylidenecyclopropanes to Allenes
Author(s) -
Trillo Beatriz,
Gulías Moisés,
López Fernando,
Castedo Luis,
Mascareñas José L.
Publication year - 2006
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200600347
Subject(s) - chemistry , intramolecular force , palladium , cycloaddition , catalysis , organic chemistry
Allenes are useful and versatile two‐carbon partners in palladium catalyzed [3C+2C] intramolecular cycloadditions with alkylidenecyclopropanes enabling the preparation of dienyl bicyclo[3.3.0]octane adducts with good yields and high diastereoseletivity.