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Activation of CCl Bonds in Chloroalkanes by Nickel Oxide Nanoparticles: Formation of Tetrasubstituted Ammonium Salts from Tertiary Amines
Author(s) -
Park Kang Hyun,
Jung Il Gu,
Chung Young Keun,
Han Jin Wook
Publication year - 2007
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200600305
Subject(s) - chemistry , catalysis , ammonium , nickel , oxide , nickel oxide , nanoparticle , inorganic chemistry , tertiary amine , organic chemistry , polymer chemistry , nanotechnology , materials science
Abstract Nickel oxide nanoparticles, readily available and easy to handle, were found to be an effective catalyst in the catalytic activation of CCl bonds in chloroalkanes. Coupling reactions of chloroalkanes and tertiary amines in the presence of the nickel oxide nanoparticle catalyst gave moderate to high yields of quaternary ammonium salts depending upon the amines.