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Productivity of Selective Electroenzymatic Reduction and Oxidation Reactions: Theoretical and Practical Considerations
Author(s) -
Ruinatscha Reto,
Höllrigl Volker,
Otto Katja,
Schmid Andreas
Publication year - 2006
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200600257
Subject(s) - chemistry , biocatalysis , limiting , biochemical engineering , redox , process (computing) , electrochemistry , nanotechnology , catalysis , process engineering , combinatorial chemistry , organic chemistry , reaction mechanism , computer science , engineering , mechanical engineering , materials science , electrode , operating system
The volumetric productivities, final product concentration and total process times, of electroenzymatic processes comprising reductive electrochemical cofactor regeneration coupled to dehydrogenase or oxygenase catalyzed redox reactions determine process performance. Exemplified for the production of fine chemicals, operational windows were defined to consider these parameters. This theoretical approach allows the identification of limiting process parameters and promising process developments. Several biocatalytic processes for syntheses of specialty chemicals are already in a performance range of technical relevance. Electroenzymology thus evolved to a strong additional technology in the toolbox of biocatalysis and organic chemistry.