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Nickel‐Catalyzed Addition of Organoboronates to 1,2‐Dienes and the Corresponding Three‐Component Reaction with an Alkyne
Author(s) -
Takahashi Go,
Shirakawa Eiji,
Tsuchimoto Teruhisa,
Kawakami Yusuke
Publication year - 2006
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200505445
Subject(s) - alkyne , chemistry , catalysis , nickel , aryl , diene , component (thermodynamics) , medicinal chemistry , conjugated diene , polymer chemistry , organic chemistry , polymer , alkyl , natural rubber , physics , monomer , thermodynamics
A Ni(cod) 2 –aminophosphine complex catalyzed the addition of aryl‐ and alkenylboronates to 1,2‐dienes to give the hydroarylation and hydroalkenylation products of the 1,2‐dienes, whereas the hydroarylation products of a 1,2‐diene and an alkyne were obtained with a Ni(cod) 2 –PPh 3 catalyst.