Nickel‐Catalyzed Addition of Organoboronates to 1,2‐Dienes and the Corresponding Three‐Component Reaction with an Alkyne | Zendy

Takahashi Go | Zendy; Shirakawa Eiji | Zendy; Tsuchimoto Teruhisa | Zendy; Kawakami Yusuke | Zendy

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Nickel‐Catalyzed Addition of Organoboronates to 1,2‐Dienes and the Corresponding Three‐Component Reaction with an Alkyne

Author(s) -

Takahashi Go,

Shirakawa Eiji,

Tsuchimoto Teruhisa,

Kawakami Yusuke

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200505445

Subject(s) - alkyne , chemistry , catalysis , nickel , aryl , diene , component (thermodynamics) , medicinal chemistry , conjugated diene , polymer chemistry , organic chemistry , polymer , alkyl , natural rubber , physics , monomer , thermodynamics

A Ni(cod) 2 –aminophosphine complex catalyzed the addition of aryl‐ and alkenylboronates to 1,2‐dienes to give the hydroarylation and hydroalkenylation products of the 1,2‐dienes, whereas the hydroarylation products of a 1,2‐diene and an alkyne were obtained with a Ni(cod) 2 –PPh 3 catalyst.

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