Asymmetric Epoxidation of Olefins by Manganese(III) Complexes Stabilised on Nanocrystalline Magnesium Oxide | Zendy

Choudary B. M. | Zendy; Pal Ujjwal | Zendy; Kantam M. Lakshmi | Zendy; Ranganath K. V. S. | Zendy; Sreedhar B. | Zendy

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Asymmetric Epoxidation of Olefins by Manganese(III) Complexes Stabilised on Nanocrystalline Magnesium Oxide

Author(s) -

Choudary B. M.,

Pal Ujjwal,

Kantam M. Lakshmi,

Ranganath K. V. S.,

Sreedhar B.

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200505428

Subject(s) - chemistry , nanocrystalline material , magnesium , manganese , enantiomer , ligand (biochemistry) , oxide , enantioselective synthesis , enantiomeric excess , inorganic chemistry , organic chemistry , medicinal chemistry , catalysis , crystallography , biochemistry , receptor

The asymmetric epoxidation of unfunctionalised olefins to epoxides is realised by using manganese(III) complexes stabilised on nanocrystalline magnesium oxide in the presence (1 R ,2 R )‐(−)‐diaminocyclohexane as a chiral ligand in good yields and up to 91 % enantiomeric excess.

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