Aerobic Oxidation of Glucose with Gold Catalyst: Hydrogen Peroxide as Intermediate and Reagent | Zendy

Comotti Massimiliano | Zendy; Della Pina Cristina | Zendy; Falletta Ermelinda | Zendy; Rossi Michele | Zendy

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Aerobic Oxidation of Glucose with Gold Catalyst: Hydrogen Peroxide as Intermediate and Reagent

Author(s) -

Comotti Massimiliano,

Della Pina Cristina,

Falletta Ermelinda,

Rossi Michele

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200505389

Subject(s) - chemistry , hydrogen peroxide , reagent , catalysis , colloidal gold , peroxide , photochemistry , redox , inorganic chemistry , organic chemistry , combinatorial chemistry , nanoparticle , nanotechnology , materials science

Careful analytical determinations show that the gold‐catalysed aerobic oxidation of glucose occurs through a two‐electrons mechanism leading to gluconate and hydrogen peroxide. This latter decomposes before reaching the critical concentration for competing with O 2 in glucose oxidation. A mechanism of glucose oxidation on gold nanoparticles is presented.

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