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Highly Stereoselective Semihydrogenation of Alkynes Promoted by Nickel(0) Nanoparticles
Author(s) -
Alonso Francisco,
Osante Iñaki,
Yus Miguel
Publication year - 2006
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200505327
Subject(s) - stereoselectivity , chemistry , nanoparticle , nickel , combinatorial chemistry , hydrogen molecule , nanotechnology , hydrogen , organic chemistry , catalysis , materials science
A new method for the highly stereoselective cis ‐semihydrogenation of internal alkynes is described based on in situ generated Ni(0) nanoparticles and molecular hydrogen. This reduction system also allows the semihydrogenation of terminal alkynes.