Rhodium‐Catalyzed Hydrosilylation of Internal Alkynes with Silane Reagents bearing Heteroatom Substituents. Studies on the Regio‐/Stereochemistry and Transformation of the Produced Alkenylsilanes by Rhodium‐Catalyzed Conjugate Addition | Zendy

Sanada Tomoyuki | Zendy; Kato Tsuyoshi | Zendy; Mitani Makoto | Zendy; Mori Atsunori | Zendy

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Rhodium‐Catalyzed Hydrosilylation of Internal Alkynes with Silane Reagents bearing Heteroatom Substituents. Studies on the Regio‐/Stereochemistry and Transformation of the Produced Alkenylsilanes by Rhodium‐Catalyzed Conjugate Addition

Author(s) -

Sanada Tomoyuki,

Kato Tsuyoshi,

Mitani Makoto,

Mori Atsunori

Publication year - 2006

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200505289

Subject(s) - hydrosilylation , rhodium , chemistry , catalysis , conjugate , heteroatom , reagent , silane , organic chemistry , medicinal chemistry , ring (chemistry) , mathematical analysis , mathematics

Rhodium‐catalyzed hydrosilylation of internal alkynes furnished ( E )‐1,2‐disubstituted alkenylsilanes. The obtained alkenylsilane was subjected to reaction with α,β‐unsaturated carbonyl compounds in the presence of a rhodium catalyst to undergo conjugate addition. One‐pot hydrosilylation‐conjugate addition with a rhodium catalyst was also performed.

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