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Pronounced Catalytic Effect of Micellar Solution of Sodium Dodecyl Sulfate (SDS) for Regioselective Iodination of Aromatic Compounds with a Sodium Iodide/Cerium(IV) Trihydroxide Hydroperoxide System
Author(s) -
Firouzabadi Habib,
Iranpoor Nasser,
Garzan Atefeh
Publication year - 2005
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200505222
Subject(s) - chemistry , regioselectivity , sodium iodide , cerium , sodium dodecyl sulfate , naphthalene , halogenation , benzene , catalysis , inorganic chemistry , sodium , organic chemistry , nuclear chemistry
Micellar solutions of sodium dodecyl sulfate (SDS) catalyze the regioselective iodination of a wide range of aromatic compounds with sodium iodide in the presence of the easily prepared, water‐resistant and recyclable cerium(IV) trihydroxide hydroperoxide, Ce(OH) 3 O 2 H, at room temperature. By this protocol, structurally diverse aromatic compounds including benzene and naphthalene were iodinated in good to excellent yields.