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Alternating Copolymerization of Cyclohexene Oxide and CO 2 Catalyzed by Zinc Complexes with New 3‐Amino‐2‐cyanoimidoacrylate Ligands
Author(s) -
Kröger Mario,
Folli Cristina,
Walter Olaf,
Döring Manfred
Publication year - 2005
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200505113
Subject(s) - chemistry , cyclohexene oxide , steric effects , zinc , catalysis , cyclohexene , copolymer , oxide , combinatorial chemistry , polymer chemistry , organic chemistry , polymer
New 3‐amino‐2‐cyanoimidoacrylate ligands with varying steric demands have been synthesized. Zinc acetate complexes of these ligands catalyze the copolymerisation of CO 2 and cyclohexene oxide, showing high activities (TOF up to over 200 h −1 ).
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