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Palladium‐Catalyzed Heck and Carbonylation Reactions of a Dinaphthaleneiodonium Salt Forming Functionalized 2‐Iodo‐1,1′‐binaphthyls
Author(s) -
Kina Asato,
Miki Hiroyuki,
Cho YongHwan,
Hayashi Tamio
Publication year - 2004
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200404202
Subject(s) - chemistry , palladium , carbonylation , heck reaction , catalysis , salt (chemistry) , organic chemistry , polymer chemistry , carbon monoxide
The Heck‐type olefination and carbonylation of a binaphthaleneiodonium salt 1 in the presence of a palladium catalyst gave high yields of the corresponding 2‐iodo‐2′‐functionalized‐1,1′‐binaphthyls with high selectivity.