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Palladium‐Carbene Catalysts for Aerobic, Intramolecular Wacker‐Type Cyclisation Reactions
Author(s) -
Muñiz Kilian
Publication year - 2004
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200404172
Subject(s) - chemistry , intramolecular force , carbene , palladium , catalysis , wacker process , photochemistry , organic chemistry , combinatorial chemistry
A catalyst derived from in situ complexation of N‐heterocyclic carbenes to palladium bistrifluoroacetate promotes efficient intramolecular Wacker‐type cyclisation reactions under aerobic conditions. A variety of 2‐allylphenols undergo oxidative conversion to dihydrobenzofurans.
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