Catalytic Carbon‐Fluorine Bond Activation with Monocoordinated Nickel‐Carbene Complexes: Reduction of Fluoroarenes | Zendy

Kuhl Sébastien | Zendy; Schneider Raphaël | Zendy; Fort Yves | Zendy

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Catalytic Carbon‐Fluorine Bond Activation with Monocoordinated Nickel‐Carbene Complexes: Reduction of Fluoroarenes

Author(s) -

Kuhl Sébastien,

Schneider Raphaël,

Fort Yves

Publication year - 2003

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200390036

Subject(s) - chemistry , carbene , imes , catalysis , nickel , reactivity (psychology) , medicinal chemistry , aryl , fluorine , photochemistry , alkoxide , organic chemistry , alkyl , medicine , alternative medicine , pathology

Monocoordinate nickel/ N ‐heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a β‐hydrogen‐containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(0)/IMes⋅HCl catalyst (IMes=1,3‐dimesitylimidazol‐2‐ylidene).

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