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Phenol and Organic Bases Co‐Catalyzed Chemical Fixation of Carbon Dioxide with Terminal Epoxides to Form Cyclic Carbonates
Author(s) -
Shen YuMei,
Duan WeiLiang,
Shi Min
Publication year - 2003
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200390035
Subject(s) - chemistry , phenol , catalysis , triethylamine , carbon dioxide , carbon fixation , pyridine , organic chemistry , carbonate , yield (engineering) , diphenyl carbonate , carboxylation , organic base , medicinal chemistry , polymer chemistry , transesterification , materials science , metallurgy
Phenol can efficiently catalyze the reactions of terminal epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases such as 4‐dimethylaminopyridine (DMAP), pyridine, 1,8‐diazabicyclo[5.4.0]undec‐7‐ene, and triethylamine to give the corresponding five‐membered cyclic carbonate in high yields (initial pressure 3.57 MPa; reaction temperature 120 °C). p ‐Methoxyphenol with DMAP is the best combination to give the cyclic carbonate in the highest yield.

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