Minor Modifications to the Ligands Surrounding a Ruthenium Complex Lead to Major Differences in the Way in which they Catalyse the Hydrogenation of Arenes | Zendy

Dyson Paul J. | Zendy; Ellis David J. | Zendy; Laurenczy Gábor | Zendy

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Minor Modifications to the Ligands Surrounding a Ruthenium Complex Lead to Major Differences in the Way in which they Catalyse the Hydrogenation of Arenes

Author(s) -

Dyson Paul J.,

Ellis David J.,

Laurenczy Gábor

Publication year - 2003

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200390014

Subject(s) - tppts , chemistry , ruthenium , catalysis , medicinal chemistry , hydroformylation , benzene , salt (chemistry) , aqueous solution , organic chemistry , rhodium

The hydrogenation of benzene and other arenes under aqueous‐organic biphasic conditions is evaluated using the ruthenium complexes Ru(η 6 ‐C 10 H 14 )(pta)Cl 2 (pta=1,3,5‐triaza‐7‐phosphaadamantane), Ru(η 6 ‐C 10 H 14 )(tppts)Cl 2 (tppts=tris‐3‐sulfonatophenylphosphine trisodium salt) and [Ru(η 6 ‐C 10 H 14 )(pta) 2 Cl] + . The active catalysts formed during the hydrogenations correspond to a trinuclear cluster, a colloid and a mononuclear complex, respectively.

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