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Amphiphilic Resin‐Supported Ruthenium(II) Complexes as Recyclable Catalysts for the Hydrogenation of Supercritical Carbon Dioxide
Author(s) -
Kayaki Yoshihito,
Shimokawatoko Yoshiki,
Ikariya Takao
Publication year - 2003
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200390007
Subject(s) - chemistry , dimethylamine , catalysis , supercritical carbon dioxide , amphiphile , ruthenium , supercritical fluid , dimethylformamide , organic chemistry , carbon dioxide , polymer chemistry , polymer , copolymer , solvent
Dichloro‐ and dihydridoruthenium(II) catalysts attached to an amphiphilic resin (PS−PEG) were prepared and tested for hydrogenation of supercritical carbon dioxide (scCO 2 ) in the presence of dimethylamine leading to N , N ‐dimethylformamide (DMF). The supported catalysts were successfully recyclable with only moderate loss of activity.