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On the Palladium(II)‐Catalysed Oxidative Rearrangement of Propargylic Acetates
Author(s) -
Bartels A.,
Mahrwald R.,
Müller K.
Publication year - 2004
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200303200
Subject(s) - chemistry , palladium , oxidative phosphorylation , catalysis , medicinal chemistry , chloride , transformation (genetics) , oxidative addition , organic chemistry , biochemistry , gene
The catalytic transformation of propargylic acetates into the corresponding α‐acetoxyenones in the presence of palladium(II) chloride is described. Water is a necessary component in this unusual oxidative rearrangement.