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Catalytic Enantioselective Oxidation of Alkanes and Alkenes Using (Salen)Manganese Complexes Bearing a Chiral Binaphthyl Strapping Unit
Author(s) -
Murahashi ShunIchi,
Noji Satoru,
Komiya Naruyoshi
Publication year - 2004
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200303190
Subject(s) - strapping , chemistry , enantioselective synthesis , indane , manganese , catalysis , hydroxylation , metal salen complexes , organic chemistry , medicinal chemistry , stereochemistry , mechanical engineering , engineering , enzyme
A (salen)manganese(III) complex bearing a chiral binaphthyl strapping unit catalyzes the enantioselective hydroxylation of indane (up to 34% ee) and the epoxidation of alkenes (up to 93% ee) with iodosylbenzene.
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