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Chemoselective Reduction of α,β‐Unsaturated Carbonyls over Novel Mesoporous CoHMA Molecular Sieves under Hydrogen Transfer Conditions
Author(s) -
Selvam P.,
Sonavane S. U.,
Mohapatra S. K.,
Jayaram R. V.
Publication year - 2004
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200303175
Subject(s) - chemistry , molecular sieve , catalysis , mesoporous material , yield (engineering) , transfer hydrogenation , mcm 41 , heterogeneous catalysis , hydrogen , hydrogen molecule , cobalt , organic chemistry , combinatorial chemistry , materials science , ruthenium , metallurgy
Chemoselective reduction of α,β ‐ unsaturated carbonyls to the corresponding alcohols was achieved by a catalytic transfer hydrogenation (CTH) method using cobalt(II)‐substituted hexagonal mesoporous aluminophosphate (CoHMA) molecular sieve catalyst. Further, the catalyst was found to be promising as a heterogeneous catalyst as the yield was practically unchanged after up to six cycles.