Chemoselective Reduction of α,β‐Unsaturated Carbonyls over Novel Mesoporous CoHMA Molecular Sieves under Hydrogen Transfer Conditions | Zendy

Selvam P. | Zendy; Sonavane S. U. | Zendy; Mohapatra S. K. | Zendy; Jayaram R. V. | Zendy

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Chemoselective Reduction of α,β‐Unsaturated Carbonyls over Novel Mesoporous CoHMA Molecular Sieves under Hydrogen Transfer Conditions

Author(s) -

Selvam P.,

Sonavane S. U.,

Mohapatra S. K.,

Jayaram R. V.

Publication year - 2004

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.200303175

Subject(s) - chemistry , molecular sieve , catalysis , mesoporous material , yield (engineering) , transfer hydrogenation , mcm 41 , heterogeneous catalysis , hydrogen , hydrogen molecule , cobalt , organic chemistry , combinatorial chemistry , materials science , ruthenium , metallurgy

Chemoselective reduction of α,β ‐ unsaturated carbonyls to the corresponding alcohols was achieved by a catalytic transfer hydrogenation (CTH) method using cobalt(II)‐substituted hexagonal mesoporous aluminophosphate (CoHMA) molecular sieve catalyst. Further, the catalyst was found to be promising as a heterogeneous catalyst as the yield was practically unchanged after up to six cycles.

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