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Free Radical‐Mediated Acylation and Carboxylation Reactions
Author(s) -
Kim Sunggak
Publication year - 2004
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200303128
Subject(s) - chemistry , carboxylation , acylation , sulfonyl , oxime , organic chemistry , carboxylic acid , radical , carbonyl group , tin , radical initiator , medicinal chemistry , catalysis , copolymer , alkyl , polymer
Abstract Radical acylations to prepare carbonyl compounds are described and focus on indirect acylation approaches using sulfonyl oxime ethers under tin‐mediated and tin‐free conditions. The efficiency of carboxylic acid derivatives as carbonyl group radical acceptors in radical acylation and carboxylation reactions is discussed.