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Suzuki–Miyaura Cross‐Coupling With Quasi‐Heterogeneous Palladium
Author(s) -
Conlon David A.,
Pipik Brenda,
Ferdinand Simone,
LeBlond Carl R.,
Sowa John R.,
Izzo Bill,
Collins Paul,
Ho GuoJie,
Williams J. Michael,
Shi YaoJun,
Sun Yongkui
Publication year - 2003
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.200303036
Subject(s) - palladium , chemistry , homogeneous , component (thermodynamics) , coupling reaction , coupling (piping) , catalysis , organic chemistry , thermodynamics , metallurgy , physics , materials science
The Suzuki–Miyaura cross‐coupling reaction using heterogeneous Pd/C has a homogeneous component. The soluble palladium concentration increases during the reaction reaching a maximum at ca. 90% conversion before falling to <4 ppm.