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From Centrosymmetry to Noncentrosymmetry: Tailoring the Structural Arrangements of Carbonates with Strong Nonlinear Optical Response through Partial Anion Substitution
Author(s) -
Meng Xianghe,
Gong Pifu,
Tang Chunlan,
Yin Wenlong,
Lin Zheshuai,
Xia Mingjun
Publication year - 2021
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.202100594
Subject(s) - materials science , birefringence , second harmonic generation , ion , planar , nonlinear optics , wavelength , nonlinear optical , phase (matter) , optoelectronics , optics , laser , nonlinear system , physics , computer graphics (images) , quantum mechanics , computer science
Second‐harmonic nonlinear‐optical (NLO) crystals with intrinsically noncentrosymmetric (NCS) structures are the core crystalline materials in the modern optics and laser technology. Here, taking as‐grown centrosymmetric NaY(CO 3 ) 2 and NCS YOHCO 3 crystals as an example, a partial anion substitution strategy in the carbonate system is provided to develop NLO materials with remarkable NLO property for the first time, while the outstanding linear optical properties such as wide bandgap and large birefringence are maintained. Notably, benefiting from the planar π‐conjugated (CO 3 ) 2− anions and closed shell electronic structure of Y 3+ cations, the YOHCO 3 crystal simultaneously manifests a deep UV cutoff (<200 nm), sturdy second‐harmonic‐generation signal (2 × KH 2 PO 4 ), and gigantic birefringence (0.07 at 1064 nm), enabling phase‐matching in short‐wavelength UV region. In addition, first‐principles calculations are conducted for the in‐depth analysis on the structure–optical property connection.