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Efficient Super Broadband NIR Ca 2 LuZr 2 Al 3 O 12 :Cr 3+ ,Yb 3+ Garnet Phosphor for pc‐LED Light Source toward NIR Spectroscopy Applications
Author(s) -
He Shuai,
Zhang Liangliang,
Wu Hao,
Wu Huajun,
Pan Guohui,
Hao Zhendong,
Zhang Xia,
Zhang Ligong,
Zhang Hong,
Zhang Jiahua
Publication year - 2020
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.201901684
Subject(s) - phosphor , materials science , light emitting diode , optoelectronics , doping , near infrared spectroscopy , excited state , spectroscopy , diode , quantum efficiency , analytical chemistry (journal) , optics , physics , chemistry , atomic physics , quantum mechanics , chromatography
Super broadband near‐infrared (NIR) phosphor converted light‐emitting diodes (pc‐LEDs) are future light sources in NIR spectroscopy applications such as food testing. At present, a few blue LED excitable super broadband NIR phosphors (bandwidth > 300 nm) have been developed producing the NIR output powers below 26 mW at 100 mA input current after LED packaging. Here, an efficient super broadband NIR phosphor achieved by doping Yb 3+ is reported in the NIR Ca 2 LuZr 2 Al 3 O 12 :Cr 3+ (CLZA:Cr 3+ ) garnet phosphor developed previously. Benefited from the superposition of Cr 3+ emission and highly efficient Yb 3+ emission excited by energy transfer from Cr 3+ , the codoped CLZA:Cr 3+ ,Yb 3+ phosphor shows a bandwidth of 320 nm and an internal quantum efficiency of 77.2% both higher than that (150 nm and 69.1%) of singly doped CLZA:Cr 3+ phosphor. The codoped phosphor converts LED produced 41.8 mW NIR output at 100 mA input current. The pc‐LED as a light source is also well applied to the NIR transmission spectra measurement of water. The results indicate the great potential of CLZA:Cr 3+ ,Yb 3+ phosphor in super broadband NIR pc‐LED applications.