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Mixed Spacer Cation Stabilization of Blue‐Emitting n = 2 Ruddlesden–Popper Organic–Inorganic Halide Perovskite Films
Author(s) -
Leung Tik Lun,
Tam Ho Won,
Liu Fangzhou,
Lin Jingyang,
Ng Alan Man Ching,
Chan Wai Kin,
Chen Wei,
He Zhubing,
Lončarić Ivor,
Grisanti Luca,
Ma Chao,
Wong Kam Sing,
Lau Ying Suet,
Zhu Furong,
Skoko Željko,
Popović Jasminka,
Djurišić Aleksandra B.
Publication year - 2020
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.201901679
Subject(s) - materials science , halide , perovskite (structure) , phase (matter) , light emitting diode , analytical chemistry (journal) , optoelectronics , crystallography , inorganic chemistry , chemistry , organic chemistry
Ruddlesden–Popper halide perovskite (RPP) materials are of significant interest for light‐emitting devices since their emission wavelength can be controlled by tuning the number of layers n , resulting in improved spectral stability compared to mixed halide devices. However, RPP films typically contain phases with different n , and the low n phases tend to be unstable upon exposure to humidity, irradiation, and/or elevated temperature which hinders the achievement of pure blue emission from n = 2 films. In this work, two spacer cations are used to form an RPP film with mixed cation bilayer and high n = 2 phase purity, improved stability, and brighter light emission compared to a single spacer cation RPP. The stabilization of n = 2 phase is attributed to favorable formation energy, reduced strain, and reduced electron–phonon coupling compared to the RPP films with only one type of spacer cation. Using this approach, pure blue light‐emitting diodes (LEDs) with Commission Internationale de l'éclairage (CIE) coordinates of (0.156, 0.088) and excellent spectral stability are achieved.