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Blue‐Pumped Deep Ultraviolet Lasing from Lanthanide‐Doped Lu 6 O 5 F 8 Upconversion Nanocrystals
Author(s) -
Du Yangyang,
Wang Yunfeng,
Deng Zhiqin,
Chen Xian,
Yang Xueqing,
Sun Tianying,
Zhang Xin,
Zhu Guangyu,
Yu Siu Fung,
Wang Feng
Publication year - 2020
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.201900968
Subject(s) - photon upconversion , materials science , lasing threshold , nanocrystal , laser , ultraviolet , optoelectronics , doping , nanotechnology , optics , wavelength , physics
Deep ultraviolet (UV) lasers are essential for enormous use ranging from medical and life science to environmental and industrial applications. Herein, a class of blue‐pumped microcavity lasers operating in the deep UV region is demonstrated by using Lu 6 O 5 F 8 :Pr/Gd@Lu 6 O 5 F 8 upconversion nanocrystals as the gain medium. A hot‐injection synthesis is developed for tuning dimensions of the Lu 6 O 5 F 8 nanocrystals. By synthesizing large‐sized nanocrystals and using inert shell coating, deep ultraviolet emission at 315 nm by blue excitation at 447 nm is realized for the first time in colloidal solutions. Mechanistic investigations suggest that the upconversion stems from sequential absorption of two blue photons by Pr 3+ ions followed by energy transfer to Gd 3+ emitters. By virtue of their small particle size and high dispersibility, the upconversion nanocrystals are readily incorporated into silica resin microcavities with a bottle‐like geometry. Lasing emissions of tunable optical characteristics are achieved from the microcavities through the formation of whispering gallery modes. These findings pave the way for constructing compact lasers operating in the deep UV regime by pumping with sophisticated long‐wavelength lasers.