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Exciton‐ and Polaron‐Induced Reversible Dipole Reorientation in Amorphous Organic Semiconductor Films
Author(s) -
Deng Chao,
Zhang Liwei,
Wang Dan,
Tsuboi Taiju,
Zhang Qisheng
Publication year - 2019
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.201801644
Subject(s) - materials science , oled , exciton , dipole , polaron , organic semiconductor , microsecond , optoelectronics , semiconductor , electric field , excited state , nanosecond , organic electronics , chemical physics , dielectric , electric dipole moment , molecular physics , electron , condensed matter physics , atomic physics , nanotechnology , optics , voltage , chemistry , physics , laser , organic chemistry , layer (electronics) , transistor , quantum mechanics
The quantum efficiency of organic light‐emitting diodes (OLEDs) employing thermally activated delayed fluorescence (TADF) highly depends on the S 1 −T 1 energy gaps (Δ E ST ) of the emitters. However, the Δ E ST values determined in solution or even in organic thin films through a static approach continuously fail in predicting device performance. Herein, by systematically investigating the time‐resolved emission spectra of several TADF emitters in various matrixes and the dielectric spectra of the matrixes, it is demonstrated that molecular organic semiconductors can undergo reversible and irreversible spatial rearrangements within a few dozen nanoseconds in an electric field created by a polarized charge‐transfer state and can in turn lower the excited‐state energy. In contrast to solution solvation, the polarized microenvironment in films can last for tens of microseconds or more after removing the electric field, leading to a narrowing and a broader distribution of Δ E ST . In TADF OLEDs, the large dipole moment of emitter‐based polarons is key for reducing the Δ E ST of subsequently generated excitons by inducing the dipole orientation of the surrounding molecules. Understanding the so‐called solid‐state solvation with a dynamic approach can provide deeper insight into the working mechanism in organic semiconductor devices.