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A High Performance Deep Blue Organic Laser Gain Material
Author(s) -
Wei Qi,
Li Yan,
Liu Jingguan,
Fang Qiyun,
Li Jiewei,
Yan Xiaohong,
Xie Linghai,
Qian Yan,
Xia Ruidong,
Huang Wei
Publication year - 2017
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.201601003
Subject(s) - lasing threshold , materials science , amplified spontaneous emission , optoelectronics , laser , gain switching , dye laser , phenylene , electron mobility , optics , polymer , composite material , wavelength , physics
High performance organic lasers with both good optical lasing property and desirable carrier mobility still remains a big challenge for realizing electrically pumped organic lasing. In this work, we have developed a carbazole‐end‐capped ladder‐type oligo‐(p‐phenylene) based hybrid oligomer as solution‐processable deep blue laser gain media to reach a good balance between optical property and carrier transporting ability, by introducing moderate steric hindrance into the pi‐conjugated planar oligo‐(p‐phenylene) backbone. This material demonstrates excellent laser performance and moderate hole mobility of 1 × 10 –3 cm 2 V −1 s −1 . The 1‐D distributed feedback (DFB) laser exhibits very low lasing threshold of 0.6 nJ pulse −1 and high slope efficiency of 5.9 ± 0.3% (50% fill factor). More importantly, the prominent ASE performance maintained at very thin film samples. The amplified spontaneous emission (ASE) threshold remains very low (16 nJ pulse −1 ) in the 45 nm‐thickness film. These results might indicate possibilities for electrically pumped gain materials.