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Quaternary Iodide K(Ca,Sr)I 3 :Eu 2+ Single‐Crystal Scintillators for Radiation Detection: Crystal Structure, Electronic Structure, and Optical and Scintillation Properties
Author(s) -
Wu Yuntao,
Li Qi,
Chakoumakos Bryan C.,
Zhuravleva Mariya,
Lindsey Adam C.,
Johnson Jesse Ashby,
Stand Luis,
Koschan Merry,
Melcher Charles L.
Publication year - 2016
Publication title -
advanced optical materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.89
H-Index - 91
ISSN - 2195-1071
DOI - 10.1002/adom.201600239
Subject(s) - scintillator , materials science , scintillation , orthorhombic crystal system , crystal (programming language) , iodide , ternary operation , crystal structure , single crystal , yield (engineering) , halide , crystallography , analytical chemistry (journal) , optoelectronics , optics , physics , chemistry , inorganic chemistry , programming language , chromatography , detector , computer science , metallurgy
A mixed crystal strategy is reported as an effective approach to improving the performances of inorganic scintillators for radiation detection applications. The aim of this work is to optimize ternary iodide KCaI 3 :Eu 2+ single crystals via partial Sr 2+ substitution, and to provide physical insights and a strategy of designing promising halide scintillators. The ∅22 mm × 50 mm long K(Ca,Sr)I 3 :Eu 2+ single crystals are grown by the Bridgman method. Crystal structure refinements verify the phase purity and the orthorhombic crystal system with a space group of Cmcm (No. 63) in the solid solutions. An energy resolution of 2.5 ± 0.1% at 662 keV and a light yield of 74 000 ± 4000 photons per MeV can be achieved for a 4 mm cube KCa 0.835 Sr 0.165 I 3 :Eu 2+ . It is for the first time that a halide solid solution is synthesized with a competitive scintillating performance as current state‐of‐the‐art scintillators, such as SrI 2 :Eu 2+ and LaBr 3 :Ce 3+ . A combination of first‐principles calculations and optical characterization experiments is employed to construct the host material band edges and the relative positions of 5 d and 4 f energy levels of the Eu 2+ activation center. The origins of the improvement of light yield and scintillation response nonproportionality are proposed from experimental and theoretical insights.