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8‐Hydroxyquinoline Metal Complexes as Cathode Interfacial Materials in Inverted Planar Perovskite Solar Cells
Author(s) -
Sun Fulin,
Liang Chunjun,
Zhang Huimin,
Ji Chao,
Song Qi,
Gong Hongkang,
Li Dan,
You Fangtian,
He Zhiqun
Publication year - 2021
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.202100506
Subject(s) - materials science , cathode , energy conversion efficiency , perovskite (structure) , layer (electronics) , optoelectronics , planar , active layer , metal , photoactive layer , chemical engineering , equivalent series resistance , ion , composite material , polymer solar cell , organic chemistry , chemistry , thin film transistor , computer graphics (images) , computer science , engineering , metallurgy , physics , quantum mechanics , voltage
Ion migration is a crucial factor influencing the stability of perovskite solar cells. Insertion of an interfacial layer between the electron‐transporting layer and the cathode is shown to be an effective way to enhance the performance of devices. However, exploring more effective interfacial materials to block ion migration and thus enhance the device stability is still needed. Herein, a series of 8‐hydroxyquinoline metal complexes are employed as cathode interfacial layers (CILs) in inverted planar perovskite solar cells. The devices with CILs exhibit better performance, stability, and reproducibility than the control device without CILs. The introduction of the CILs forms a better energy match between the [6,6]‐phenyl‐C61‐butyric acid methyl ester layer and the cathode, reduces the contact resistance, accelerates the charge transfer, and suppresses non‐radiative recombination. Moreover, the CILs protect the device from moisture and block the ion diffusions, which is beneficial for device stability. After optimization, the best power conversion efficiency of 20.6% is obtained by using 8‐hydroxyquinoline aluminum (Alq 3 ) as a CIL, and the efficiency remains 85% of its initial value after 800 h continuous illumination.