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Mg‐Doped VO 2 @ZrO 2 Core−Shell Nanoflakes for Thermochromic Smart Windows with Enhanced Performance
Author(s) -
Wen Zuohao,
Ke Yujie,
Feng Chengchen,
Fang Shuliang,
Sun Miuyang,
Liu Xinghai,
Long Yi
Publication year - 2021
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.202001606
Subject(s) - thermochromism , materials science , hydrothermal circulation , doping , wetting , shell (structure) , nanotechnology , core (optical fiber) , nanocrystal , chemical engineering , optoelectronics , composite material , chemistry , organic chemistry , engineering
The VO 2 ‐based smart windows can dynamically and reversibly adjust the indoor solar irradiation to reduce the energy consumption for building glasses. This paper reports the first successful preparation of Mg‐doped VO 2 @ZrO 2 core−shell nanocrystals with promoted thermochromic performance as well as tunable appearance and wettability. The achieved combination of T lum of 52.4% and ∆ T sol of 7.1% is comparable to the best‐reported results of VO 2 ‐based core−shell rod structures. The thickness of ZrO 2 shell is tunable between 3 and 14 nm, resulting in a slightly hydrophobic surface and a slight color change toward blue‐green and brighter produced films. The preparation method based on hydrothermal and UV‐curing methods is facile. This work may inspire future development of VO 2 synthesis, their structure−property, and the application the thermochromic films for energy‐saving purposes in buildings or automobiles.