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Ultrathin‐Walled 3D Inorganic Nanostructured Networks Templated from Cross‐Linked Cellulose Nanocrystal Aerogels
Author(s) -
Hiltunen Arto,
Or Tyler,
Lahtonen Kimmo,
AliLöytty Harri,
Tkachenko Nikolai,
Valden Mika,
Sarlin Essi,
Cranston Emily D.,
MoranMirabal Jose M.,
Vapaavuori Jaana
Publication year - 2021
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.202001181
Subject(s) - materials science , aerogel , atomic layer deposition , fabrication , nanocrystal , nanotechnology , calcination , nanoporous , nanostructure , coating , substrate (aquarium) , layer (electronics) , catalysis , chemical engineering , medicine , biochemistry , chemistry , alternative medicine , oceanography , pathology , geology , engineering
A key challenge in the development of materials for applications in the fields of opto‐ and nanoelectronics, catalysis, separation, and energy conversion is the ability to fabricate 3D inorganic semiconductive nanostructures in a precisely‐controlled and cost‐effective manner. This work describes the fabrication of 3D nanostructured TiO 2 monoliths by coating ultraporous cross‐linked cellulose nanocrystal (CNC) aerogel templates with TiO 2 layers of controlled thickness via atomic layer deposition (ALD). Following calcination, the resulting hollow inorganic ultraporous 3D networks form the thinnest self‐supporting semiconductive structure (7 nm) fabricated directly on a conductive substrate. The CNC‐templated ALD–TiO 2 electrodes are applied toward photoelectrochemical water splitting. The results show that a TiO 2 coating as thin as 15 nm produces a maximum water splitting efficiency, resulting in materials savings and reduced fabrication time.