Premium
Aggregation‐Induced Emission Luminogens for Direct Exfoliation of 2D Layered Materials in Ethanol
Author(s) -
Zhao Yu,
Gao Wei,
Yang Yibin,
Zhang Haoke,
Redshaw Carl,
Feng Xing,
Li Jingbo,
Lam Jacky W. Y.,
Tang Ben Zhong
Publication year - 2020
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.202000795
Subject(s) - materials science , exfoliation joint , nanotechnology , aggregation induced emission , layer (electronics) , graphene , optics , physics , fluorescence
Abstract Aggregation‐induced emission (AIE) luminogens are an important type of advanced functional materials with fantastic optical properties and have found potential applications in organic electronics, biochemistry, and molecular imaging. Herein, this article presents a novel application of AIE luminogens (AIEgens) for efficient exfoliation of layered transition metal dichalcogenides (TMDs, such as MoS 2 and WSe 2 ). From the 1 H NMR spectroscopic analysis, the designed AIEgens can insert into the space between layers of MoS 2 in ethanol solution and the dynamic molecular rotation against the weak interactions affords large‐scale few‐layer MoS 2 nanosheets (7–8 layers) with enhanced smoothness. The 3D AIEgens play a significant role in preserving the crystal lattice of MoS 2 even at high pressure (>15 GPa). More importantly, the new approach can also be used for exfoliation of WSe 2 to achieve large‐scale few‐layer nanosheets. The present work thus provides a facile and high yielding synthetic method for accessing on a large scale 2D layered materials with enhanced properties for high‐technology applications.