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A Fluorescence Probe for Metal Ions Based on Black Phosphorus Quantum Dots
Author(s) -
Xu Zhenyu,
Hu Liang,
Yuan Jun,
Zhang Yiyue,
Guo Yujie,
Jin Zhengyuan,
Long Fangchao,
Long Yaojia,
Liang Huawei,
Ruan Shuangchen,
Zeng YuJia
Publication year - 2020
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201902075
Subject(s) - fluorescence , aqueous solution , metal ions in aqueous solution , quantum yield , materials science , quantum dot , ion , quenching (fluorescence) , adsorption , photoluminescence , molecule , inorganic chemistry , metal , detection limit , photochemistry , analytical chemistry (journal) , nanotechnology , chemistry , organic chemistry , optoelectronics , physics , chromatography , metallurgy , quantum mechanics
Fluorescence method for detecting metal ions has advantages of fast detection speed, simple operation, and low price over the conventional methods. Black phosphorus quantum dots (BP QDs) have high photoluminescence quantum yield and modifiable surface, which have great potential in the field of fluorescent probes. In this study, high quality BP QDs are prepared by pyrolysis method and are first time used as trace metal ion probes in both organic solutions and aqueous solutions. The detection limits of Hg 2+ and Cu 2+ in the aqueous solution are 5.3 × 10 −9 m and 1.6 × 10 −6 m , respectively. In addition, the detection limits of Cu 2+ in the organic solution are 16 × 10 −6 m . The fluorescence quenching mechanism based on the calculation of the electronic structure and adsorption energy of BP QDs after adsorption of metal ions is further explained. The results provide a new promising fluorescence probe for trace metal ions without the help of organic molecules.