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Structure‐Dependent Wear and Shear Mechanics of Nanostructured MoS 2 Coatings
Author(s) -
Serles Peter,
Sun Hao,
Colas Guillaume,
Tam Jason,
Nicholson Eric,
Wang Guorui,
Howe Jane,
Saulot Aurélien,
Singh Chandra Veer,
Filleter Tobin
Publication year - 2020
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201901870
Subject(s) - materials science , composite material , van der waals force , lubricant , nanostructure , nanoindentation , tribology , fracture mechanics , nanocrystalline material , shear (geology) , nanotechnology , chemistry , organic chemistry , molecule
Sputter‐deposited molybdenum disulfide coatings are one of the most common lubricants for extreme environments. However, their performance predictability remains limited by the complexity of van der Waals wear and shear mechanics in bulk materials resulting in unexpected premature failure. In the present study, two nanostructured MoS 2 coatings of similar macroscopic properties are shown to exhibit entirely different wear and shear mechanics due to their nanostructure. Friction force microscopy with steel‐beaded cantilevers is used to measure the per‐cycle evolution of friction, wear, and topography in situ over the lubricant lifetime under an inert nitrogen environment. Molecular dynamics simulations confirm the subsurface structural failure mechanisms of the coatings under shear stress, and atomic force microscope phase imaging and Raman spectroscopy are used to identify tribofilm formation mechanics. The nanocrystal–amorphous composite structure shows improved wear resistance but at the cost of limited stress relaxation which creates high‐stress failure and fracture‐dominated wear. The purely nanocrystalline coating exhibits lower shear resistance but consistent stress relaxation by van der Waals cleavage and triple junction fracture which results in higher wear rates with predictable abrasion‐dominated failure. The contrast in nanoscale performance of the coatings allows for the lubricant nanostructure to be tuned for ideal applications for extreme environments.