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Enhanced Uniformity and Stability of Pb–Sn Perovskite Solar Cells via Me 4 NBr Passivation
Author(s) -
Du Xingzhi,
Qiu Renzheng,
Zou Taoyu,
Chen Xuexian,
Chen Huanjun,
Zhou Hang
Publication year - 2019
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201900413
Subject(s) - passivation , perovskite (structure) , materials science , halide , tin , chemical engineering , perovskite solar cell , degradation (telecommunications) , open circuit voltage , energy conversion efficiency , solar cell , optoelectronics , inorganic chemistry , nanotechnology , metallurgy , voltage , chemistry , electronic engineering , layer (electronics) , physics , quantum mechanics , engineering
Tin–lead (Sn–Pb) based hybrid perovskite solar cell is investigated as a potential solution to extend the light absorption spectrum range, and to reduce environmental hazard caused by lead in the perovskite materials. Nonetheless, due to the instability of tin, the Sn–Pb based perovskite solar cells suffer from more severe efficiency degradation when compared to the lead‐based perovskite solar cells, which restricts its further development. Here, a quaternary ammonium halide compound, Me 4 NBr, is introduced to passivate the Sn–Pb based perovskite surface. The Me 4 NBr effectively reduces the surface defects and enhances the open circuit voltage and fill factor of the Sn–Pb based perovskite solar cell. Moreover, the Me 4 NBr treated Sn–Pb perovskite cells also demonstrate a significant stability enhancement when compared with the untreated Sn–Pb perovskite cells.