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Grain Boundary Engineering Nanostructured SrTiO 3 for Thermoelectric Applications
Author(s) -
Dylla Maxwell T.,
Kuo Jimmy Jiahong,
Witting Ian,
Snyder Gerald Jeffrey
Publication year - 2019
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201900222
Subject(s) - materials science , grain boundary , thermoelectric effect , crystallite , thermoelectric materials , thermal conductivity , interfacial thermal resistance , ceramic , electrical resistivity and conductivity , grain growth , phase (matter) , electrical resistance and conductance , condensed matter physics , grain size , composite material , nanotechnology , engineering physics , thermal resistance , thermal , microstructure , metallurgy , thermodynamics , electrical engineering , physics , chemistry , organic chemistry , engineering
Abstract Nanostructuring to reduce thermal conductivity is among the most promising strategies for designing next‐generation, high‐performance thermoelectric materials. In practice, electrical grain boundary resistance can overwhelm the thermal conductivity reduction induced by nanostructuring, which results in worse overall performance. Since a large body of work has characterized the transport of both polycrystalline ceramics and single crystals of SrTiO 3 , it is an ideal material system for conducting a case study of electrical grain boundary resistance. An effective mass model is used to characterize the transport signatures of electrical grain boundary resistance and evaluate thermodynamic design principles for controlling that resistance. Treating the grain boundary as a secondary phase to the bulk crystallites explains the transport phenomena. Considering that the interface can be engineered by controlling oxygen partial pressure, temperature, and the addition of extrinsic elements into the grain boundary phase, the outlook for SrTiO 3 as a nanostructured thermoelectric is promising, and the zT could be greater than 0.5 at room temperature.