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2D Patterned Ion‐Exchange Membranes Induce Electroconvection
Author(s) -
Roghmans Florian,
Evdochenko Elizaveta,
Stockmeier Felix,
Schneider Sven,
Smailji Amel,
Tiwari Rahul,
Mikosch Annabel,
Karatay Elif,
Kühne Alexander,
Walther Andreas,
Mani Ali,
Wessling Matthias
Publication year - 2019
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201801309
Subject(s) - limiting current , membrane , concentration polarization , materials science , electrodialysis , polystyrene , vortex , chemical physics , desalination , laminar flow , ion , ion transporter , microscale chemistry , electrolyte , limiting , chemical engineering , nanotechnology , mechanics , composite material , polymer , electrode , chemistry , electrochemistry , biochemistry , physics , organic chemistry , engineering , mechanical engineering , mathematics education , mathematics
Concentration polarization is a diffusion‐limited phenomenon for ion transport in electrodialysis based desalination processes. Once a so‐called limiting current is reached, the resistance of the system rises notably manifested as a plateau region in the current–voltage curves. For long it is hypothesized that altering the surface properties of the membrane can overcome the diffusional transport limitation by the induction of electroconvective vortices mixing the laminar boundary layer. To systematically investigate the influence of geometrical and chemical membrane surface topology on the evolution of electroconvection, circular patterns of polystyrene, poly(2‐vinylpyridine) (P2VP), and P2VP microgels are inkjet printed on cation‐exchange membranes. All types of patterns cause an insignificant increase in membrane resistance but they reduce the plateau lengths indicating the desired accelerated onset of electroconvection. In case of polystyrene (PS) patterns, the drop in plateau length results in a small reduction in transport resistance for overlimiting currents. However, membranes modified with linear P2VP and P2VP microgel patterns do exhibit a significantly decreased resistance in this region at a simultaneous increase of the limiting current density. Direct numerical simulations support the interpretation that the surface charge of the printed patterns influences the direction of the vortices being advantageous during ion transport toward the membrane.