Premium
Amino‐Functionalized Multilayer Core–Shell Mesoporous Organosilica Nanospheres for Cr(VI) Removal
Author(s) -
Lai Xin,
Sun Dan,
Hou Yi,
Zuo Yi,
Li Yubao,
Zhang Li
Publication year - 2018
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201800630
Subject(s) - adsorption , diethylenetriamine , materials science , mesoporous material , mesoporous silica , chemical engineering , metal ions in aqueous solution , shell (structure) , metal , nanotechnology , inorganic chemistry , organic chemistry , catalysis , chemistry , composite material , metallurgy , engineering
Developing low‐cost and highly efficient adsorbents for the removal of toxic heavy metal ions is the subject of intensive research with the increasingly stringent water pollution control standards. In this paper, three types of amino‐functionalized multilayer core–shell mesoporous organosilica nanospheres (MCMONs) are synthesized using an indirect cocondensation method for Cr(VI) removal applications. Results show that amino groups are successfully immobilized on the nanospheres and these amino‐functionalized MCMONs exhibit unique organic–inorganic multilayer core–shell structures. When used as adsorbent for Cr(VI) removal, the N‐(3‐trimethoxysilylpropyl)diethylenetriamine functionalized MCMONs exhibit a maximum adsorption capacity of 279.92 mg g −1 at initial Cr(VI) concentration of 150 mg L −1 . This is about 20% greater than the highest Cr(VI) adsorption capacity previously reported for other core–shell silica‐based adsorbents, demonstrating the great potential of MCMONs in Cr(VI) removal applications.