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Sandwich‐Like FeCl 3 @C as High‐Performance Anode Materials for Potassium‐Ion Batteries
Author(s) -
Li Deping,
Zhu Min,
Chen Lina,
Chen Long,
Zhai Wei,
Ai Qing,
Hou Guangmei,
Sun Qing,
Liu Yang,
Liang Zhen,
Guo Shirui,
Lou Jun,
Si Pengchao,
Feng Jinkui,
Zhang Lin,
Ci Lijie
Publication year - 2018
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201800606
Subject(s) - anode , materials science , electrode , intercalation (chemistry) , current density , graphene , raman spectroscopy , graphite , potassium , chemical engineering , transmission electron microscopy , electrochemistry , nanotechnology , inorganic chemistry , composite material , metallurgy , chemistry , physics , engineering , quantum mechanics , optics
Carbon materials are used as the anode materials of potassium‐ion batteries (KIBs) thanks to the feasible intercalation of potassium ions. However, their rate capability and cycling performance are still unsatisfactory. In this work, FeCl 3 ‐intercalated expanded graphite (FeCl 3 ‐EG) is first reported as an excellent anode material of KIBs. Attributed to the unique structure with FeCl 3 sandwiched between the adjacent graphene layers, the FeCl 3 ‐EG electrode delivers a high reversible capacity of 269.5 mAh g −1 at 50 mA g −1 and 133.1 mAh g −1 at an ultrahigh current density of 5000 mA g −1 . The FeCl 3 ‐EG electrode also exhibits an ultrastable cycling performance. Even after 500 cycles at the current density of 50 mA g −1 , the FeCl 3 ‐EG electrode can still deliver a discharge capacity of 224.1 mAh g −1 with a high capacity retention of ≈88.82%. Moreover, the FeCl 3 ‐EG electrode is measured at an ultrahigh current density of 2000 mA g −1 for 1300 cycles, with a high capacity retention of ≈70.38%. Ex situ X‐ray diffraction, Raman, and high‐resolution transmission electron microscopy measurements are performed to investigate the potassium storage mechanism of FeCl 3 ‐EG electrode, which confirms the FeCl 3 ‐EG a promising anode material for high‐performance KIBs.