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Stable 2D Conductive Ga/Ga(O x H y ) Multilayers with Controlled Nanoscale Thickness Prepared from Gallium Droplets with Oxide Skin
Author(s) -
Runde Sebastian,
Ahrens Heiko,
Lawrenz Frank,
Sebastian Amal,
Block Stephan,
Helm Christiane A.
Publication year - 2018
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201800323
Subject(s) - materials science , gallium , deposition (geology) , wafer , layer (electronics) , electrical resistivity and conductivity , conductivity , electrical conductor , oxide , nanometre , heterojunction , nanotechnology , optoelectronics , nanoscopic scale , atomic layer deposition , composite material , metallurgy , paleontology , chemistry , engineering , sediment , electrical engineering , biology
The practical applicability of ultrathin films, which offer interesting and novel functionalities, is often limited by difficulties in achieving large area deposition while maintaining homogenous layer properties. Herein, a new deposition method allowing ultrathin, conductive gallium‐containing layers to be prepared at ambient conditions on wafer‐scaled areas is presented. Multilayers are formed by repetition of the deposition procedure. High‐resolution structural analysis using X‐ray reflectometry shows that the multilayer thickness is proportional to the number of deposition cycles, yielding a highly reproducible single layer thickness of 2.9 ± 0.2 nm. Furthermore, it is shown that single layers consist of a complex heterostructure composed of a nanometer‐thin metallic Ga core, which is surrounded by stabilizing gallium (hydr)oxide skin layers. The macroscopic electric conductivity of these multilayers increases with increasing number of deposited layers, approaching the value of bulk gallium after six deposition cycles, thereby showing that functional properties such as the multilayer's electrical conductivity can be fine‐tuned based on the chosen number of deposition cycles.