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Controlled Selective CVD Growth of ZnO Nanowires Enabled by Mask‐Free Fabrication Approach using Aqueous Fe Catalytic Inks
Author(s) -
Alameri Dheyaa,
Ocola Leonidas E.,
Kuljanshvili Irma
Publication year - 2017
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201700950
Subject(s) - materials science , fabrication , nanowire , nanotechnology , chemical vapor deposition , aqueous solution , catalysis , zinc , deposition (geology) , metallurgy , chemistry , medicine , alternative medicine , pathology , biochemistry , paleontology , sediment , biology
Fabrication process that enables selective growth of vertically oriented zinc oxide (ZnO) nanowires (NWs) via chemical vapor deposition method and mask‐free patterning approach is reported. It is shown that synthesis of high‐quality ZnO nanowires in various architectures is achievable by optimizing the growth conditions and by precise patterning of catalytic ink precursors. Parallel direct‐write patterning method is utilized to fabricate arrays of different architectures on Si/SiO 2 substrates and directly on devices at preselected locations. The production of high‐quality, crystalline ZnO NWs is demonstrated using aqueous iron catalytic inks. The composition of the ink and the lateral size of the patterns deposited on substrates are shown to affect the resulting nanowires and thus, allowing to control the geometry (length and diameter) of the individual ZnO NWs in the patterned assemblies. The results indicate that our protocols are tailored to the fabrication of ZnO NWs with specific surface geometries and interface functionalities for variety of targeted device applications.