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Enhanced Stability and Electrochemical Performance of Carbon‐Coated Ti 3+ Self‐Doped TiO 2 ‐Reduced Graphene Oxide Hollow Nanostructure‐Supported Pt‐Catalyzed Fuel Cell Electrodes
Author(s) -
Sung Chang Hyun,
Boppella Ramireddy,
Yoo JaiWook,
Lim DongHee,
Moon ByungMoo,
Kim Dong Ha,
Kim Jin Young
Publication year - 2017
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201700564
Subject(s) - materials science , graphene , electrochemistry , oxide , catalysis , chemical engineering , electrolyte , electrocatalyst , proton exchange membrane fuel cell , cathode , carbon fibers , carbon black , direct ethanol fuel cell , electrode , nanotechnology , composite material , fuel cells , composite number , metallurgy , chemistry , organic chemistry , natural rubber , engineering
Stable alternative catalyst supports to replace conventional carbon‐based materials in polymer electrolyte membrane fuel cells (PEMFCs) are being explored to achieve dramatic improvements in the performance and durability of fuel cells. Herein, conductive Ti 3+ self‐doped and carbon‐coated TiO 2 ‐reduced graphene oxide (rGO) hollow nanosphere‐supported Pt nanoparticles (Pt/rGO/TiO 2 ) are investigated as cathode electrocatalysts for PEMFCs. Importantly, the rGO/TiO 2 hollow nanospheres display excellent electrochemical stability under high potential cycling (1.2–1.7 V) compared with conventional carbon black (CB) support materials that normally induce electrochemical corrosion during fuel cell operation. The Pt/rGO/TiO 2 is tested to establish its catalytic activity and stability using accelerated durability testing that mimics the conditions and degradation modes encountered during long‐term fuel cell operation. The Pt/rGO/TiO 2 cathode catalyst demonstrates comparable catalytic activity toward oxygen reduction and exhibits much higher stability than the Pt/CB one at high potentials in terms of minimal loss of the Pt electrochemical surface area. More importantly, Pt/rGO/TiO 2 displays a negligible voltage drop over long‐term cycling during practical fuel cell operation. The high stability of the Pt/rGO/TiO 2 electrocatalyst synthesized in this investigation offers a new approach to improve the reliability and durability of PEMFC cathode catalysts.