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The Mechanistic Insights into the 2H‐1T Phase Transition of MoS 2 upon Alkali Metal Intercalation: From the Study of Dynamic Sodiation Processes of MoS 2 Nanosheets
Author(s) -
Huang Qianming,
Li Xiaomin,
Sun Muhua,
Zhang Lei,
Song Chenzhi,
Zhu Liang,
Chen Pan,
Xu Zhi,
Wang Wenlong,
Bai Xuedong
Publication year - 2017
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201700171
Subject(s) - materials science , intercalation (chemistry) , superstructure , transition metal , phase transition , alkali metal , phase (matter) , chemical physics , transmission electron microscopy , ion , electron transfer , nanotechnology , crystallography , inorganic chemistry , chemistry , condensed matter physics , thermodynamics , catalysis , physics , biochemistry , organic chemistry
Phase transition in 2D MoS 2 is an important issue in transition metal dichalcogenides. The mechanism of the phase transition is investigated extensively, while a comprehensive understanding of the mechanism remains to be elusive. The 2H to 1T phase transition of MoS 2 can be induced by intercalation with alkali metals, associated with transformation of its electronic and structural orders. Here, by using in situ transmission electron microscopy, the electrochemical sodiation processes of MoS 2 nanosheets are investigated. This paper points out an intermediate phase 2H‐Na 0.25 MoS 2 with 2 × √3 superstructure. The phase transition occurs from 2H‐Na 0.5 MoS 2 to 1T‐Na 0.5 MoS 2 , where the ratio of Mo 3+ and Mo 4+ is 1:1 and intervalence charge transfer (IVCT) between the two ions should not be neglected. Based on this viewpoint it is proposed that the IVCT plays an important role in the formation of the phase transition. The findings provide a new perspective on the mechanism of the phase transition, and help to better understand the phase transition mechanism of other transition metal dichalcogenides.