Premium
Role of Water in the Dynamic Crystallization of CuTCNQ for Enhanced Redox Catalysis (TCNQ = Tetracyanoquinodimethane)
Author(s) -
Siu Mark C.,
Anderson Samuel R.,
Mohammadtaheri Mahsa,
Ahmed Taimur,
Walia Sumeet,
Ramanathan Rajesh,
Bansal Vipul
Publication year - 2017
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201700097
Subject(s) - tetracyanoquinodimethane , catalysis , redox , materials science , crystallization , nanotechnology , dissolution , chemical engineering , phase (matter) , molecule , organic chemistry , chemistry , engineering , metallurgy
A new bisolvent approach is introduced to overcome the limitation of wet chemical routes of a semiconducting phase I CuTCNQ (7,7,8,8‐tetracyanoquinodimethane) synthesis, which currently does not allow these materials to be grown beyond certain dimensions (10–15 µm). The use of water as a cosolvent during acetonitrile‐mediated conventional synthesis of CuTCNQ allows a dynamic control over its crystallization and dissolution process through favorably shifting the reaction equilibrium. This enables CuTCNQ structures of unique morphologies with secondary growth, alongside dimensions exceeding 100 µm to be produced. These new morphologies of phase I CuTCNQ show remarkable promise in redox catalysis over their conventional counterparts by facilitating efficient charge transfer at the catalyst–reactant interface. As catalytic, sensing, and electronic performance of materials strongly depend upon their morphological characteristics, the concepts introduced here have potential applicability for controllable fabrication of a range of metal‐organic charge transfer complexes of technological importance.