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Mimosa Pudica Leaf‐Like Rapid Movement and Actuation of Organosoluble Polyimide Blending with Sulfonated Polyaniline
Author(s) -
Tseng IHsiang,
Li JhengJia,
Chang PoYa
Publication year - 2017
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201600901
Subject(s) - polyimide , polyaniline , materials science , curling , composite material , electrochromism , moisture , polymer , chemical engineering , electrode , layer (electronics) , chemistry , engineering , polymerization
Like the thigmonastic responses of the leaves of Mimosa pudica , the curling of organosoluble and free‐standing polyimide (PI) films under the stimuli of fingertip‐touching or air‐blowing is discovered for the first time. The authors discover that the PI films at the dry status can rapidly and reversibly attract and release water molecules at the interface of the thin film in response to the changes of environmental humidity. The moisture‐triggered heterogeneous deformation across the film leads to self‐curling of PI films. With the blending of suitable amounts of sulfonated‐polyaniline (PANI‐S) to the PI matrix, the resultant PANI‐S/PI film can more effectively breath water from the air and simultaneously create more significant deformation and faster recovery. With the suitable designed patterns on the film, it can serve a highly sensitive and reliable actuator to grasp and release subjects as well as to fold into 3D structures, and to roll like a tank tread by providing trace moisture gradients. This robust PANI‐S/PI film can be cast into any shape or coated on various substrates and thus is a promising material for smart delivery systems in industrial applications.