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Separation‐Free Polyaniline/TiO 2 3D Hydrogel with High Photocatalytic Activity
Author(s) -
Jiang Wenjun,
Liu Yanfang,
Wang Jun,
Zhang Mo,
Luo Wenjiao,
Zhu Yongfa
Publication year - 2016
Publication title -
advanced materials interfaces
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.671
H-Index - 65
ISSN - 2196-7350
DOI - 10.1002/admi.201500502
Subject(s) - polyaniline , materials science , photocatalysis , aniline , nanocomposite , adsorption , composite number , chemical engineering , polymerization , nanostructure , self healing hydrogels , nanoparticle , in situ polymerization , nanotechnology , composite material , polymer , polymer chemistry , catalysis , organic chemistry , chemistry , engineering
A polyaniline (PANI) hydrogel with 3D network nanostructure is synthesized by polymerizing aniline. TiO 2 nanoparticles are located onto the 3D matrix of the PANI hydrogel. This PANI/TiO 2 composite 3D hydrogel is efficient in removing organic contaminants owing to the synergistic effect of adsorption‐enrichment and the succedent in situ photocatalytic degradation. In this process, organic contaminant is first adsorbed and enriched onto the surface of the TiO 2 nanoparticles through 3D network nanostructure of PANI hydrogel. The organic contaminant is then in situ degraded. The 3D network structured PANI/TiO 2 composite hydrogel has the advantage of high reactivity in nano‐sized materials and possesses the characteristics of separation‐free in bulk materials, indicating that the composite hydrogel is ease of recycling. Overall, this work provides new insights into the fabrication of hydrogel‐based nanocomposite materials and facilitates their potential application for the synergistic removal of various aquatic pollutants in the field of water purification.