Lithium‐Assisted Proton Conduction at 150 °C in a Microporous Triazine‐Phenol Polymer | Zendy

Nandi Shyamapada | Zendy; Dhavale Vishal M. | Zendy; Shalini Sorout | Zendy; WernerZwanziger Ulrike | Zendy; Singh Harpreet | Zendy; Kurungot Sreekumar | Zendy; Vaidhyanathan Ramanathan | Zendy

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Lithium‐Assisted Proton Conduction at 150 °C in a Microporous Triazine‐Phenol Polymer

Author(s) -

Nandi Shyamapada,

Dhavale Vishal M.,

Shalini Sorout,

WernerZwanziger Ulrike,

Singh Harpreet,

Kurungot Sreekumar,

Vaidhyanathan Ramanathan

Publication year - 2015

Publication title -

advanced materials interfaces

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.671

H-Index - 65

ISSN - 2196-7350

DOI - 10.1002/admi.201500301

Subject(s) - microporous material , electrolyte , lithium (medication) , triazine , materials science , phenol , polymer , residual , chemical engineering , proton , polymer electrolytes , polymer science , organic chemistry , polymer chemistry , chemistry , ionic conductivity , computer science , composite material , physics , medicine , electrode , algorithm , quantum mechanics , engineering , endocrinology

A practically nonconducting triazine‐phenol polymer with high surface‐hydrophobicity is transformed into a proton conducting electrolyte by tunable Li + loading. The high hydration tendency of the Li + enables the retention of residual waters assisting conductivities as high as 1.63 × 10 −3 S cm −1 even at 150 ºC. The crucial role of residual water is rationalized by comparing the conductivities in D 2 O and H 2 O.

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