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Sub‐Nanometer Nanobelts Based on Titanium Dioxide/Zirconium Dioxide–Polyoxometalate Heterostructures
Author(s) -
Zhang Simin,
Liu Nan,
Wang Hongwei,
Lu Qichen,
Shi Wenxiong,
Wang Xun
Publication year - 2021
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.202100576
Subject(s) - nanoclusters , polyoxometalate , materials science , catalysis , nanometre , titanium dioxide , heterojunction , nanotechnology , zirconium dioxide , chemical engineering , organic chemistry , chemistry , optoelectronics , engineering , metallurgy , composite material
In addition to offering conformational flexibility, sub‐nanometer nanobelts (SNBs) also outperform many larger nanobelts with large size owing to their ultrathin morphologies. However, to date, only a few monocomponent SNBs have been synthesized. This study presents a facile method for synthesizing ZrO 2 –PMoO (PMZ) SNBs and TiO 2 –PMoO (PMT) SNBs with heterostructures. The SNBs comprise ZrO 2 /TiO 2 and polyoxometalate (POM) nanoclusters, which are formed via the aggregation and subsequent transformation of nanoclusters. Significantly, these SNBs demonstrate high catalytic activity and stability in oxidative desulfurization reactions at room temperature. The impressive catalytic performance of the SNBs is aided by the POM nanoclusters, which not only coassemble with ZrO 2 /TiO 2 nuclei to form building blocks of PMZ SNBs/PMT SNBs but also serve as catalytic centers. The catalytic performance is further enhanced by the ZrO 2 /TiO 2 in the SNBs. Moreover, the proposed synthesis method can be utilized to produce other SNBs. Thus, this method provides valuable insights into the strong performance properties of SNBs created by combining metal oxides and POM nanoclusters into SNBs, which have great potential as redox catalysts.