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Metal–Organic Frameworks: Boosting Catalysis of Pd Nanoparticles in MOFs by Pore Wall Engineering: The Roles of Electron Transfer and Adsorption Energy (Adv. Mater. 30/2020)
Author(s) -
Chen Dongxiao,
Yang Weijie,
Jiao Long,
Li Luyan,
Yu ShuHong,
Jiang HaiLong
Publication year - 2020
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.202070225
Subject(s) - metal organic framework , materials science , nanoparticle , adsorption , electron transfer , catalysis , benzoic acid , nanotechnology , chemical engineering , metal , energy transfer , organic chemistry , chemistry , chemical physics , engineering , metallurgy
The isoreticular metal–organic framework (MOF) UiO‐66‐X with diverse functional groups, encapsulating guest Pd nanoparticles, is fabricated by H.‐L. Jiang and co‐workers, as described in article number 2000041. The chemical microenvironment around the Pd is systematically regulated by these MOF hosts, giving rise to distinctly different performances toward the hydrogenation of benzoic acid.