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Ionic Hydrogen‐Bonded Organic Frameworks for Ion‐Responsive Antimicrobial Membranes
Author(s) -
Liu BaiTong,
Pan XiaoHong,
Nie DanYue,
Hu XiaoJing,
Liu EnPing,
Liu TianFu
Publication year - 2020
Publication title -
advanced materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.707
H-Index - 527
eISSN - 1521-4095
pISSN - 0935-9648
DOI - 10.1002/adma.202005912
Subject(s) - counterion , membrane , materials science , surface modification , ionic bonding , porphyrin , hydrogen bond , antimicrobial , biocide , chemical engineering , polymer , ion , nanotechnology , organic chemistry , molecule , chemistry , composite material , biochemistry , engineering
Functionalization of hydrogen‐bonded organic frameworks (HOFs) for specific applications has been a long‐lasting challenge in HOF materials. Here, an efficient way to integrate functional species in the HOF structure through constructing an anionic framework is presented. The obtained HOFs, taking PFC‐33 (PFC = porous materials from FJIRSM,CAS) as an example, integrate a porphyrin photosensitizer as a porous backbone and a commercial biocide as counterions in the structure. The permanent channels and the electrostatic interaction between the framework and the counterions provide PFC‐33 ion‐responsive biocide‐release behavior in various physiological environments, thus exhibiting synergistic photodynamic and chemical antimicrobial efficiency. The unbonded carboxyl groups residing on the HOF surface further allow for manipulating the interfacial interaction between the PFC‐33 and the polymer matrix for membrane fabrication. Therefore, a polyHOF membrane with high stability, desired flexibility, and good permeability is obtained, which demonstrates noticeable bacterial inhibition toward Escherichia coli . This study may shed light on the functionalization of HOF materials for broad application potentials.